NFE-766
Rejeição: Item com CST indevido [nItem: …] (CST …).
In English An NF-e with the DANFE Simplificado Tipo 2 has an ICMS CST outside 00, 20, 40, 41, 60, 61 and 90.
What the rule checks
As the rule set's publisher wrote it. The rule runs on every element the context matches, and fails where the test is false; the validator reports the line of that element.
nfe:infNFe/nfe:det
not($simple and $cst) or $cst = ('00', '20', '40', '41', '60', '61', '90')
Checked with NF-e 4.00, NF-e 4.00 with authorisation protocol